Di-μ-chlorido-bis{bis[3,5-dimethylpyrazol-1-yl-κN 2)methane]iron(II)} bis[tetrachloridoferrate(III)]
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چکیده
In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl-pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa-hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis-(3,5-dimethyl-pyrazol-1-yl)methane ligands. The Fe(III) atom has a tetra-hedral coordination geometry comprising four chloride anions.
منابع مشابه
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The mol-ecule of the title compound, [Cu(2)(SO(4))(2)(C(11)H(16)N(4))(2)], sits on a center of symmetry. The Cu(II) atom has a distorted trigonal-bipyramidal coordination geometry comprising three O atoms of the two symmetry-related SO(4) (2-) anions and two N atoms from one bis-(3,5-dimethyl-pyrazol-1-yl)methane ligand.
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